I think you may be getting confused by different programming languages' naming strategies.

There's a class of data types known as "floating point numbers". Two floating-point number types defined by IEEE-754 are "binary32" and "binary64". In C and C++, those two types are exposed as the types float and double, respectively. In Python, only "binary64" is natively supported as a built-in type; it's known as float.

Python's struct module supports both binary32 and binary64, and uses C/C++'s nomenclature to refer to them. f specifies binary32 and d specifies binary64. Regardless of which you're using, the module packs from and unpacks to Python's native float type (which, remember, is binary64). In the case of d that's exact; in the case of f it converts the type under the hood. You don't need to fool Python into doing the conversion.

Now, I'm just going to assume you're wrong about "stored as hex of double". What I think you probably mean is "stored as double" -- namely, 64 bits in a file -- as opposed to stored as "hex of double", namely sixteen human-readable ASCII characters. That latter one just doesn't happen.

All of which is to say, if you want to store things as binary64, it's just a matter of struct.pack('d', value).

Answer from Sneftel on Stack Overflow
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Solved: convert float to double! - Esri Community
November 14, 2012 - You can create a new field of type Double, and then use the Field Calculator to calculate the values from the Float field to the new Double field. ... TopoToRaster's input can be float, integer or double.
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