When you need to iterate over files in folder with similar names one of the ways could be make a pattern and use glob. To make sure that returned path is file you can use isfile().

Regarding XML, I see that basically you need to write values of every terminal tag in column with name of this tag. As you have various files you can create tag-value dictionaries from each file and store them into ChainMap. After all files processed you can use DictWriter to write all data into final csv file.

This method is much more safe and flexible then use static column names. Firstly program will collect all possible tag(column) names from all files, so in case if XML doesn't have such a tag or have some extra tags it won't throw an exception and all data will be saved.

Code:

import xml.etree.ElementTree as ET
from glob import iglob
from os.path import isfile, join
from csv import DictWriter
from collections import ChainMap

xml_root = r"C:\data\Desktop\Blue\XML-files"
pattern = "xmlfile_*"
data = ChainMap()
for filename in iglob(join(xml_root, pattern)):
    if isfile(filename):
        tree = ET.parse(filename)
        root = tree.getroot()
        temp = {node.tag: node.text for node in root.iter() if not node}
        data = data.new_child(temp)

with open(join(xml_root, "data.csv"), "w", newline="") as f:
    writer = DictWriter(f, data)
    writer.writeheader()
    writer.writerows(data.maps[:-1])  # last is empty dict

Upd. If you want to use xlsx format instead of csv you have to use third-party library (e.g. openpyxl). Example of usage:

from openpyxl import Workbook

...

wb = Workbook(write_only=True)
ws = wb.create_sheet()
ws.append(list(data))  # write header
for row in data.maps[:-1]:
    ws.append([row.get(key, "") for key in data])
wb.save(join(xml_root, "data.xlsx"))

MattDMo has given a sufficient answer to the problem, but I just want to remind you that python has a csv module which makes it easier to write comma separated data, which is typically then read into applications such as databases or spreadsheets.

From the docs:

import csv
with open('eggs.csv', 'wb') as csvfile:
    spamwriter = csv.writer(csvfile, delimiter=' ',
                        quotechar='|', quoting=csv.QUOTE_MINIMAL)
    spamwriter.writerow(['Spam'] * 5 + ['Baked Beans'])
    spamwriter.writerow(['Spam', 'Lovely Spam', 'Wonderful Spam'])

Finally I could figure this out using win32com.client module.

I used the following code successfully to import an xml to an existing Excel xlsx file I use as template, and then save it with a different name:

import win32com.client as win32
excel = win32.gencache.EnsureDispatch('Excel.Application')
wb = excel.Workbooks.Open("D:/tmp/template.xlsx")
wb.XmlImport("D:/tmp/result.xml")
wb.SaveAs("D:\\tmp\\result.xlsx")
wb.Close()

Methods for Excel workbooks can be found here. Also I had to take into account that the saveAs method doesn't support forward slashes.