I suggest not to rely on the raw PYTHONPATH because it can vary depending on the OS.

Instead of the PYTHONPATH value in the os.environ dict, use sys.path from the sys module. This is preferrrable, because it is platform independent:

import sys
print(sys.path)

The value of sys.path is initialized from the environment variable PYTHONPATH, plus an installation-dependent default (depending on your OS). For more info see

https://docs.python.org/2/library/sys.html#sys.path

https://docs.python.org/3/library/sys.html#sys.path

You would probably also want this:

import sys
print(sys.path)

Or as a one liner from the terminal:

python -c "import sys; print('\n'.join(sys.path))"

Caveat: If you have multiple versions of Python installed you should use a corresponding command python2 or python3.

python -c "import sys; print (sys.path)"

Typically, the environment variable $PYTHONPATH is empty (try echo $PYTHONPATH). The actual list of folders python searches for libraries can be found with (in python):

import sys
print(sys.path)

This will consist (in search order) of the current directory, any directories in your $PYTHONPATH, and finally the default library directories, set by site.py. The main default locations are (where X.Y is the python version, eg 2.7):

/usr/lib/pythonX.Y (python system libraries, eg re, urllib)
/usr/lib/pythonX.Y/dist-packages (python libraries installed with deb packages)

If you use pip install --user or similar to install libraries as yourself, it will also contain the user library directory:

/home/USERNAME/.local/lib/pythonX.Y/site-packages

You can manipulate the PYTHONPATH by either setting the environment variable before you launch python (PYTHONPATH=$PYTHONPATH:/foo/bar), or by editing sys.path once you've started python (import sys; sys.path = ["/foo/bar"] + sys.path).

However, if you want to play with your own python libraries, a good idea is to create a virtualenv. This is a directory in which you can play around with your own versions of python libraries without any risk of messing up the python libraries used by the system. See How to set up and use a virtual python environment in Ubuntu? for information about creating and using a virtualenv.

sys.path in Python is a "list of strings that specifies the search path for modules. Initialized from the environment variable PYTHONPATH, plus an installation-dependent default." (taken from the Python online documentation).

For sys.path to be affected by PYTHONPATH, the latter has to be an environment variable. If it's not an environment variable but just a shell variable, it will not be visible by the python interpreter. You turn it into an environment variable by exporting it after setting its value, or at the same time, as in

export PYTHONPATH=/some/path:/goes/here