(The above answers explained the reason quite clearly, but seems not totally clear about the size of padding, so, I will add an answer according to what I learned from The Lost Art of Structure Packing, it has evolved to not limit to C, but also applicable to Go, Rust.)

Memory align (for struct)

Rules:

• Before each individual member, there will be padding so that to make it start at an address that is divisible by its alignment requirement.
  E.g., on many systems, an int should start at an address divisible by 4 and a short by 2.
• char and char[] are special, could be any memory address, so they don't need padding before them.
• For struct, other than the alignment need for each individual member, the size of whole struct itself will be aligned to a size divisible by strictest alignment requirement of any of its members, by padding at end.
  E.g., on many systems, if struct's largest member is int then by divisible by 4, if short then by 2.

Order of member:

• The order of member might affect actual size of struct, so take that in mind. E.g., the stu_c and stu_d from example below have the same members, but in different order, and result in different size for the 2 structs.

Address in memory (for struct)

Empty space:

• Empty space between 2 structs could be used by non-struct variables that could fit in.
  e.g in test_struct_address() below, the variable x resides between adjacent struct g and h.
  No matter whether x is declared, h's address won't change, x just reused the empty space that g wasted.
  Similar case for y.

Example

(for 64 bit system)

memory_align.c:

/**
 * Memory align & padding - for struct.
 * compile: gcc memory_align.c
 * execute: ./a.out
 */ 
#include <stdio.h>

// size is 8, 4 + 1, then round to multiple of 4 (int's size),
struct stu_a {
    int i;
    char c;
};

// size is 16, 8 + 1, then round to multiple of 8 (long's size),
struct stu_b {
    long l;
    char c;
};

// size is 24, l need padding by 4 before it, then round to multiple of 8 (long's size),
struct stu_c {
    int i;
    long l;
    char c;
};

// size is 16, 8 + 4 + 1, then round to multiple of 8 (long's size),
struct stu_d {
    long l;
    int i;
    char c;
};

// size is 16, 8 + 4 + 1, then round to multiple of 8 (double's size),
struct stu_e {
    double d;
    int i;
    char c;
};

// size is 24, d need align to 8, then round to multiple of 8 (double's size),
struct stu_f {
    int i;
    double d;
    char c;
};

// size is 4,
struct stu_g {
    int i;
};

// size is 8,
struct stu_h {
    long l;
};

// test - padding within a single struct,
int test_struct_padding() {
    printf("%s: %ld\n", "stu_a", sizeof(struct stu_a));
    printf("%s: %ld\n", "stu_b", sizeof(struct stu_b));
    printf("%s: %ld\n", "stu_c", sizeof(struct stu_c));
    printf("%s: %ld\n", "stu_d", sizeof(struct stu_d));
    printf("%s: %ld\n", "stu_e", sizeof(struct stu_e));
    printf("%s: %ld\n", "stu_f", sizeof(struct stu_f));

    printf("%s: %ld\n", "stu_g", sizeof(struct stu_g));
    printf("%s: %ld\n", "stu_h", sizeof(struct stu_h));

    return 0;
}

// test - address of struct,
int test_struct_address() {
    printf("%s: %ld\n", "stu_g", sizeof(struct stu_g));
    printf("%s: %ld\n", "stu_h", sizeof(struct stu_h));
    printf("%s: %ld\n", "stu_f", sizeof(struct stu_f));

    struct stu_g g;
    struct stu_h h;
    struct stu_f f1;
    struct stu_f f2;
    int x = 1;
    long y = 1;

    printf("address of %s: %p\n", "g", &g);
    printf("address of %s: %p\n", "h", &h);
    printf("address of %s: %p\n", "f1", &f1);
    printf("address of %s: %p\n", "f2", &f2);
    printf("address of %s: %p\n", "x", &x);
    printf("address of %s: %p\n", "y", &y);

    // g is only 4 bytes itself, but distance to next struct is 16 bytes(on 64 bit system) or 8 bytes(on 32 bit system),
    printf("space between %s and %s: %ld\n", "g", "h", (long)(&h) - (long)(&g));

    // h is only 8 bytes itself, but distance to next struct is 16 bytes(on 64 bit system) or 8 bytes(on 32 bit system),
    printf("space between %s and %s: %ld\n", "h", "f1", (long)(&f1) - (long)(&h));

    // f1 is only 24 bytes itself, but distance to next struct is 32 bytes(on 64 bit system) or 24 bytes(on 32 bit system),
    printf("space between %s and %s: %ld\n", "f1", "f2", (long)(&f2) - (long)(&f1));

    // x is not a struct, and it reuse those empty space between struts, which exists due to padding, e.g between g & h,
    printf("space between %s and %s: %ld\n", "x", "f2", (long)(&x) - (long)(&f2));
    printf("space between %s and %s: %ld\n", "g", "x", (long)(&x) - (long)(&g));

    // y is not a struct, and it reuse those empty space between struts, which exists due to padding, e.g between h & f1,
    printf("space between %s and %s: %ld\n", "x", "y", (long)(&y) - (long)(&x));
    printf("space between %s and %s: %ld\n", "h", "y", (long)(&y) - (long)(&h));

    return 0;
}

int main(int argc, char * argv[]) {
    test_struct_padding();
    // test_struct_address();

    return 0;
}

Execution result - test_struct_padding():

stu_a: 8
stu_b: 16
stu_c: 24
stu_d: 16
stu_e: 16
stu_f: 24
stu_g: 4
stu_h: 8

Execution result - test_struct_address():

stu_g: 4
stu_h: 8
stu_f: 24
address of g: 0x7fffd63a95d0  // struct variable - address dividable by 16,
address of h: 0x7fffd63a95e0  // struct variable - address dividable by 16,
address of f1: 0x7fffd63a95f0 // struct variable - address dividable by 16,
address of f2: 0x7fffd63a9610 // struct variable - address dividable by 16,
address of x: 0x7fffd63a95dc  // non-struct variable - resides within the empty space between struct variable g & h.
address of y: 0x7fffd63a95e8  // non-struct variable - resides within the empty space between struct variable h & f1.
space between g and h: 16
space between h and f1: 16
space between f1 and f2: 32
space between x and f2: -52
space between g and x: 12
space between x and y: 12
space between h and y: 8

Thus address start for each variable is g:d0 x:dc h:e0 y:e8

I assume that by "packing" you mean removing the padding, using a non-standard pragma or attribute (such as Gcc's __attribute__((packed))). There are two main reasons you might do this:

1. Reduce memory allocation. If you will be allocating a large number of objects, the extra allocation due to the padding may be significant.
2. To make the in-memory layout reflect the layout on-disk (when dealing with particular file formats for example) or in a particular protocol. This may allow reading and writing the structure object directly, rather than having to deal separately with each field. (Byte order within individual fields may still be a concern).

In general, the practice is not portable and you should avoid it unless you have a very good reason.

In many cases it is possible to reduce the padding required by re-organizing your data structure: put the largest members first, and then place following members in decreasing order of size.