A good book I'm reading: Professional JavaScript for Web Developers by Nicholas C. Zakas 3rd Edition has the following information regarding JSON Syntax:

"JSON Syntax allows the representation of three types of values".

Regarding the one you're interested in, Arrays it says:

"Arrays are represented in JSON using array literal notation from JavaScript. For example, this is an array in JavaScript:

var values = [25, "hi", true];

You can represent this same array in JSON using a similar syntax:

[25, "hi", true]

Note the absence of a variable or a semicolon. Arrays and objects can be used together to represent more complex collections of data, such as:

{
    "books":
              [
                {
                    "title": "Professional JavaScript",
                    "authors": [
                        "Nicholas C. Zakas"
                    ],
                    "edition": 3,
                    "year": 2011
                },
                {
                    "title": "Professional JavaScript",
                    "authors": [
                        "Nicholas C.Zakas"
                    ],
                    "edition": 2,
                    "year": 2009
                },
                {
                    "title": "Professional Ajax",
                    "authors": [
                        "Nicholas C. Zakas",
                        "Jeremy McPeak",
                        "Joe Fawcett"
                    ],
                    "edition": 2,
                    "year": 2008
                }
              ]
}

This Array contains a number of objects representing books, Each object has several keys, one of which is "authors", which is another array. Objects and arrays are typically top-level parts of a JSON data structure (even though this is not required) and can be used to create a large number of data structures."

To serialize (convert) a JavaScript object into a JSON string you can use the JSON object stringify() method. For the example from Mark Linus answer:

var cars = [{
    color: 'gray',
    model: '1',
    nOfDoors: 4
    },
    {
    color: 'yellow',
    model: '2',
    nOfDoors: 4
}];

cars is now a JavaScript object. To convert it into a JSON object you could do:

var jsonCars = JSON.stringify(cars);

Which yields:

"[{"color":"gray","model":"1","nOfDoors":4},{"color":"yellow","model":"2","nOfDoors":4}]"

To do the opposite, convert a JSON object into a JavaScript object (this is called parsing), you would use the parse() method. Search for those terms if you need more information... or get the book, it has many examples.