Pandas DataFrame columns are Pandas Series when you pull them out, which you can then call x.tolist() on to turn them into a Python list. Alternatively you cast it with list(x).

Copyimport pandas as pd

data_dict = {'one': pd.Series([1, 2, 3], index=['a', 'b', 'c']),
             'two': pd.Series([1, 2, 3, 4], index=['a', 'b', 'c', 'd'])}

df = pd.DataFrame(data_dict)

print(f"DataFrame:\n{df}\n")
print(f"column types:\n{df.dtypes}")

col_one_list = df['one'].tolist()

col_one_arr = df['one'].to_numpy()

print(f"\ncol_one_list:\n{col_one_list}\ntype:{type(col_one_list)}")
print(f"\ncol_one_arr:\n{col_one_arr}\ntype:{type(col_one_arr)}")

Output:

DataFrame:
   one  two
a  1.0    1
b  2.0    2
c  3.0    3
d  NaN    4

column types:
one    float64
two      int64
dtype: object

col_one_list:
[1.0, 2.0, 3.0, nan]
type:<class 'list'>

col_one_arr:
[ 1.  2.  3. nan]
type:<class 'numpy.ndarray'>