You would probably also want this:

import sys
print(sys.path)

Or as a one liner from the terminal:

python -c "import sys; print('\n'.join(sys.path))"

Caveat: If you have multiple versions of Python installed you should use a corresponding command python2 or python3.

Typically, the environment variable $PYTHONPATH is empty (try echo $PYTHONPATH). The actual list of folders python searches for libraries can be found with (in python):

import sys
print(sys.path)

This will consist (in search order) of the current directory, any directories in your $PYTHONPATH, and finally the default library directories, set by site.py. The main default locations are (where X.Y is the python version, eg 2.7):

/usr/lib/pythonX.Y (python system libraries, eg re, urllib)
/usr/lib/pythonX.Y/dist-packages (python libraries installed with deb packages)

If you use pip install --user or similar to install libraries as yourself, it will also contain the user library directory:

/home/USERNAME/.local/lib/pythonX.Y/site-packages

You can manipulate the PYTHONPATH by either setting the environment variable before you launch python (PYTHONPATH=$PYTHONPATH:/foo/bar), or by editing sys.path once you've started python (import sys; sys.path = ["/foo/bar"] + sys.path).

However, if you want to play with your own python libraries, a good idea is to create a virtualenv. This is a directory in which you can play around with your own versions of python libraries without any risk of messing up the python libraries used by the system. See How to set up and use a virtual python environment in Ubuntu? for information about creating and using a virtualenv.

$env:PYTHONPATH = $pwd

You forgot a colon in the last version. Also the . doesn't work here, but you can use the built-in variable $pwd (current directory).

I find $env:NAME the easiest way to get environment variables in Powershell. It also follows the Microsoft documentation: about_Environment_Variables.

Try appending to PYTHONPATH instead of overwriting it completely.

export PYTHONPATH=$PYTHONPATH:/home/dev/python-files

References:

According to the the Python documentation on PYTHONPATH

Augment the default search path for module files. [...]

The default search path is installation dependent, but generally begins with prefix/lib/pythonversion (see PYTHONHOME above). It is always appended to PYTHONPATH.

meaning that some values exist in PYTHONPATH and the default search path is also only appended.

Additionally, this blog post (Archive.org link) also explains clearly why you need to append to PYTHONPATH and not overwrite it. Scrolling down to the section - Special cases and examining the search path explains it clearly (unfortunately no relative URL to that link so you'll have to scroll). Although the user gives the examples on a mac they are very much relevant to any platform