Basically what you do is correct. Looking at redmine docs you linked to, it seems that suffix after the dot in the url denotes type of posted data (.json for JSON, .xml for XML), which agrees with the response you get - Processing by AttachmentsController#upload as XML. I guess maybe there's a bug in docs and to post binary data you should try using http://redmine/uploads url instead of http://redmine/uploads.xml.

Btw, I highly recommend very good and very popular Requests library for http in Python. It's much better than what's in the standard lib (urllib2). It supports authentication as well but I skipped it for brevity here.

import requests
with open('./x.png', 'rb') as f:
    data = f.read()
res = requests.post(url='http://httpbin.org/post',
                    data=data,
                    headers={'Content-Type': 'application/octet-stream'})

# let's check if what we sent is what we intended to send...
import json
import base64

assert base64.b64decode(res.json()['data'][len('data:application/octet-stream;base64,'):]) == data

UPDATE

To find out why this works with Requests but not with urllib2 we have to examine the difference in what's being sent. To see this I'm sending traffic to http proxy (Fiddler) running on port 8888:

Using Requests

import requests

data = 'test data'
res = requests.post(url='http://localhost:8888',
                    data=data,
                    headers={'Content-Type': 'application/octet-stream'})

we see

POST http://localhost:8888/ HTTP/1.1
Host: localhost:8888
Content-Length: 9
Content-Type: application/octet-stream
Accept-Encoding: gzip, deflate, compress
Accept: */*
User-Agent: python-requests/1.0.4 CPython/2.7.3 Windows/Vista

test data

and using urllib2

import urllib2

data = 'test data'    
req = urllib2.Request('http://localhost:8888', data)
req.add_header('Content-Length', '%d' % len(data))
req.add_header('Content-Type', 'application/octet-stream')
res = urllib2.urlopen(req)

we get

POST http://localhost:8888/ HTTP/1.1
Accept-Encoding: identity
Content-Length: 9
Host: localhost:8888
Content-Type: application/octet-stream
Connection: close
User-Agent: Python-urllib/2.7

test data

I don't see any differences which would warrant different behavior you observe. Having said that it's not uncommon for http servers to inspect User-Agent header and vary behavior based on its value. Try to change headers sent by Requests one by one making them the same as those being sent by urllib2 and see when it stops working.

The curl -d switch sends a POST request, but you are using requests.get() instead, sending a GET request (whose body is ignored).

Make it a POST instead, by using request.post():

import requests
import json

url = "http://cdcnepal.com/Modules/HOmeMoviesLists/WebService2.asmx/GetShowsByDate"
headers = {"content-type": "application/json; charset=UTF-8"}
payload = {"portalId":"1","showDate":"26/05/2014","flag":0,"size":9}
r = requests.post(url, headers=headers, data=json.dumps(payload))
print r.text

You also need to:

1. not use a list for the content-type header, there is no support for paramaters being specified separately.
2. Encode your JSON data to a JSON string; requests doesn't do this for you. Instead, a dictionary passed to data is encoded as application/x-www-form-urlencoded data instead.

You can compare the curl command with requests more easily using http://httpbin.org/post:

$ curl http://httpbin.org/post \
>  -H 'Content-Type: application/json; charset=UTF-8' \
>  -d '{"portalId":"1","showDate":"26/05/2014","flag":0,"size":9}'

{
  "args": {},
  "data": "{\"portalId\":\"1\",\"showDate\":\"26/05/2014\",\"flag\":0,\"size\":9}",
  "files": {},
  "form": {},
  "headers": {
    "Accept": "*/*",
    "Connection": "close",
    "Content-Length": "58",
    "Content-Type": "application/json; charset=UTF-8",
    "Host": "httpbin.org",
    "User-Agent": "curl/7.30.0",
    "X-Request-Id": "78d7bb7d-e29b-482b-908a-48d2395a050f"
  },
  "json": {
    "flag": 0,
    "portalId": "1",
    "showDate": "26/05/2014",
    "size": 9
  },
  "origin": "84.92.98.170",
  "url": "http://httpbin.org/post"
}

and

>>> import requests
>>> import json
>>> from pprint import pprint
>>> url = 'http://httpbin.org/post'
>>> headers = {"content-type":"application/json; charset=UTF-8"}
>>> payload = {"portalId":"1","showDate":"26/05/2014","flag":0,"size":9}
>>> r = requests.post(url, headers=headers, data=json.dumps(payload))
>>> pprint(r.json())
{u'args': {},
 u'data': u'{"portalId": "1", "flag": 0, "size": 9, "showDate": "26/05/2014"}',
 u'files': {},
 u'form': {},
 u'headers': {u'Accept': u'*/*',
              u'Accept-Encoding': u'gzip, deflate, compress',
              u'Connection': u'close',
              u'Content-Length': u'65',
              u'Content-Type': u'application/json; charset=UTF-8',
              u'Host': u'httpbin.org',
              u'User-Agent': u'python-requests/2.2.1 CPython/2.7.6 Darwin/13.1.0',
              u'X-Request-Id': u'06d6b542-c279-4898-8701-2c0d502aa36e'},
 u'json': {u'flag': 0,
           u'portalId': u'1',
           u'showDate': u'26/05/2014',
           u'size': 9},
 u'origin': u'84.92.98.170',
 u'url': u'http://httpbin.org/post'}

Both cases show the same json dictionary being returned.

If you are using requests version 2.4.2 or newer, you can also leave the JSON encoding to the library; it'll set the correct Content-Type header too, if you pass in the data to send as the json keyword argument:

import requests

url = "http://cdcnepal.com/Modules/HOmeMoviesLists/WebService2.asmx/GetShowsByDate"
payload = {"portalId":"1","showDate":"26/05/2014","flag":0,"size":9}
r = requests.post(url, json=payload)
print r.text

To call the binary methods, you have to send raw binary data as an application/octet-stream in the request body and read the binary data sent back in the response body.

There's a StackOverflow answer that shows making binary requests using Python here. Quoting the requests library example:

import requests

data = 'test data'
res = requests.post(url='http://localhost:8888',
                data=data,
                headers={'Content-Type': 'application/octet-stream'})

Here you would replace data with the binary tx id (which is 32 bytes), wrapped as a Levin packet. A brief overview can be found here.

For working out how to serialize the request data and deserialize the returned response data, you should start by looking in this folder.

Here is an annotated response for the interested:

0111010101010201        signature
01                      version
0c                      section
09 6f5f696e6465786573   field: string length then data: o_indexes
85                      type (uint64 | array flag)
08                      length 2 (0x08 >> 2)
aca87f0000000000        idx
ada87f0000000000        idx
06 737461747573         field: string length then data: status
0a                      type (string)
08                      length 2 (0x08 >> 2)
4f4b                    OK
09 756e74727573746564   field: string length then data: untrusted
0b                      type (bool)
00                      false

Here is a quick and dirty example of calling then parsing the response using Python.

it may because you use multipart/form to upload file.try use data like code below

data = open(localFilePath, 'rb').read()
headers = {
    "Content-Type":"application/binary",
}
upload = requests.put(uploadUrl,data=data,headers=headers)