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Chemistry LibreTexts
chem.libretexts.org › campus bookshelves › lumen learning › book: statistics for the social sciences (lumen) › 3: 2- summarizing data graphically and numerically
3.13: Standard Deviation (2 of 4) - Chemistry LibreTexts
September 26, 2020 - However, we will always use technology to perform the actual computation of the standard deviation. The symbols in the expression are defined as follows: n is the number of values in the data set (the count). Recall that ∑ means to add up (compute the sum). ... The individual values are denoted by x. ... Before we learn to use technology to compute the standard deviation, we practice estimating it.
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Chemical Dictionary
chemicool.com › definition › standard_deviation.html
Definition of standard_deviation - Chemistry Dictionary
The quantity (xi - ) is called the "residual" or the "deviation from the mean" for each measurement. The quantity (N - 1) is called the "degrees of freedom" for the measurement. ... The relative standard deviation (RSD) is useful for comparing the uncertainty between different measurements ...
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Calculator.net
calculator.net › home › math › standard deviation calculator
Standard Deviation Calculator
This free standard deviation calculator computes the standard deviation, variance, mean, sum, and error margin of a given data set.
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Utoronto
sites.chem.utoronto.ca › chemistry › coursenotes › analsci › stats › MeasMeanVar.html
Statistics in Analytical Chemistry - Stats (3)
Use the worksheet from exercise 1 to also calculate the variance and standard deviation of the sodium values by setting up a formula. You will need to create a column to calculate individual values of before calculating s2 and s. Compare your standard deviation and variance with those calculated using the built-in STDEV and VAR functions.
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Chemistry LibreTexts
chem.libretexts.org › campus bookshelves › bethune-cookman university › bcu: ch-346 instrumental analysis › bcu: ch 346 lab manual › introductory details
Statistical Treatment of Data - Chemistry LibreTexts
August 11, 2020 - where xi is the result of the ith measurement, i = 1,…,N. The standard deviation, σ, measures how closely values are clustered about the mean. The standard deviation for small samples is defined by:
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Openochem
learn.openochem.org › learn › general-chemistry › standard-deviation-calculations
Standard Deviation Calculations | OpenOChem Learn
Calculate the Variance: The variance is the square of the deviation. In cells D6:D10 are the variance for each measurement. ... Examine the formula in cells C6 to C10. Calculate the Standard Deviation: The standard deviation is the square root of the average variance.
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WHO
extranet.who.int › hslp › who-hslp-download › package › 501 › material › 192 pdf
Annex : Calculation of Mean and Standard Deviation
5. Calculate the variance and standard deviation: (see formulas below) a. Subtract each data point from the mean and write in column B. b. Square each value in column B and write in column C. c. Add column C. Result is 71 mg/dL. d. Now calculate the variance: Divide the sum in column C by n-1 which is 19.
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But what standard deviation is small enough to be considered precise?

"Sufficiently precise," ironically enough, is something that can't really be defined precisely in general terms.

In other words, a level of precision that is perfectly fine in one context might be unacceptably low in others.

For example, if I'm trying to estimate how much table salt I need to buy to supply my catering business for the next six months, I might be perfectly happy with a not-very-precise calculation at $\pm\,30\%$, since salt is cheap and will keep just fine if I buy too much.

On the other hand, if I'm a pharmacist compounding a prescription containing a drug where the level in the body leading to nasty side effects is not all that much higher than the level that provides the desired pharmacological activity, I probably want to use (and am probably required by law to use!) methods and apparatus that'll give me, say, $\pm\,3\%$ precision on my measurements.


Is there a better method for quantifying precision?

Not really. Pretty much every metric I've seen for quantifying precision involves the standard deviation in some way. Depending on the situation, one might use:

  • $s$, the standard deviation by itself

  • $s/\bar x$, the standard deviation divided by the mean, also called the relative standard deviation or coefficient of variation (CV)

  • $s/\!\left(\bar x \sqrt n\right)$, the relative standard deviation divided by the square root of the number of measurements

    • This is equal to the standard error $\left(s/\!\sqrt n\right)$ divided by the mean

The "Comparison to standard deviation" subsection of the Wikipedia article on the coefficient of variation lists some situations where these different quantities would be useful relative to others.


From this standard deviation, would this experiment's results be considered precise?

If not, why not, and how would I interpret it?

In my opinion: Yes, these results are precise. In this case, since the mean value is far from zero and there's only one dataset being examined, I would use the coefficient of variation (CV) as my metric of precision. With these values, I get a CV of $1.88\%$. On the whole, I think this is an entirely reasonable CV for a titration experiment. The data could exhibit more precision, obviously, but that low of a CV implies very good repeatability to me.

As porphyrin noted, that $\pu{17.1 mL}$ measurement you obtained is perfectly reasonable in a statistical sense, as it's $25\%$ of a small dataset, residing $1.7$ standard deviations away from the mean. This puts it well line with the expected $32\%$ occurrence of values $x$ where $|x-\bar x|/s > 1.0$.

In other words, I disagree with Mithoron: I don't think that value is an outlier at all. The usual metric I'm familiar with for identifying outliers is where $|x-\bar x|/s > 3.0$, which should occur only $\approx 0.34\%$ of the time for normally-distributed data.


The uncertainty of the burette is $\pm\,\pu{0.05 mL}$.

A brief note: I believe the small uncertainty on the burette as compared to the standard deviation in your data $(0.05 / 0.38 \approx 13\%)$ indicates that the majority of the spread in your measurements comes from elements of the experimental apparatus/procedure other than the burette.


Further reading: This article at Inorganic Ventures is a good writeup of the mean and standard deviation, and how they relate (or not) to accuracy and precision.

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LabCE
labce.com › spg113775_mean_and_standard_deviation.aspx
Mean and Standard Deviation - LabCE.com, Laboratory Continuing Education
The mean is calculated by adding all values and dividing by the number of values. The formula is · For example, suppose you wanted to find the mean of the values 4, 6, 2, 8, and 5. The mean is · The standard deviation (abbreviated s or SD) is calculated according to the following formula:
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IUPAC
goldbook.iupac.org › terms › view › S05911
IUPAC - standard deviation (S05911)
The standard deviation is the positive square root of the variance, a more fundamental statistical quantity. Source: Orange Book, 2nd ed., p. 5 [Terms] [Book] See also: PAC, 1990, 62, 2167. (Glossary of atmospheric chemistry terms (Recommendations 1990)) on page 2216 [Terms] [Paper] PAC, 1994, ...
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ThoughtCo
thoughtco.com › how-to-calculate-standard-deviation-608322
Learn How to Calculate Standard Deviation
November 22, 2019 - There are two main ways to calculate standard deviation: population standard deviation and sample standard deviation. If you collect data from all members of a population or set, you apply the population standard deviation. If you take data that represents a sample of a larger population, you apply the sample standard deviation formula.
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Sisu
sisu.ut.ee › measurement › 33-standard-deviation-mean
3.4. Standard deviation of the mean – Estimation of measurement uncertainty in chemical analysis
The standard deviation s (V ) calculated using the formula 3.3 is the standard deviation of an individual pipetting result (value). When the mean value is calculated from a set of individual values which are randomly distributed then the mean value will also be a random quantity.
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Inorganic Ventures
inorganicventures.com › icp-guide › accuracy-precision-mean-and-standard-deviation
Accuracy, Precision, Mean and Standard Deviation
The above definition is for estimating the standard deviation for n values of a sample of a population and is always calculated using n-1. The standard deviation of a population is symbolized as s and is calculated using n. Unless the entire population is examined, s cannot be known and is estimated from samples randomly selected from it. For example, an analyst may make four measurements upon a given production lot of material (population). The standard deviation of the set (n=4) of measurements would be estimated using (n-1).
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UTSA Department of Mathematics
mathresearch.utsa.edu › wiki › index.php
Standard Deviation - Department of Mathematics at UTSA
Standard Deviation Formula, Statistics, Variance, Sample and Population Mean, The Organic Chemistry Tutor