There are two string methods for this, find() and index(). The difference between the two is what happens when the search string isn't found. find() returns -1 and index() raises a ValueError.

Using find()

>>> myString = 'Position of a character'
>>> myString.find('s')
2
>>> myString.find('x')
-1

Using index()

>>> myString = 'Position of a character'
>>> myString.index('s')
2
>>> myString.index('x')
Traceback (most recent call last):
  File "<stdin>", line 1, in <module>
ValueError: substring not found

From the Python manual

string.find(s, sub[, start[, end]])
Return the lowest index in s where the substring sub is found such that sub is wholly contained in s[start:end]. Return -1 on failure. Defaults for start and end and interpretation of negative values is the same as for slices.

And:

string.index(s, sub[, start[, end]])
Like find() but raise ValueError when the substring is not found.

You just need to index the string, just like you do with a list.

>>> 'hello'[3]
l

Note that Python indices (like most other languages) are zero based, so the first element is index 0, the second is index 1, etc.

For example:

>>> 'hello'[0]
h
>>> 'hello'[1]
e