/src/main/resources is a Maven project structure convention. It's a path inside your project where you place resources. During the build step, Maven will take files in there and place them in the appropriate place for you to use them in your runtime classpath, eg in an executable .jar, some physical file system location used in the classpath (with java's -cp option), etc.

I could choose to build my application myself or with a different build tool. In such a case, /src/main/resources would not exist. However, the intention is for the classpath to be the same, ie. to contain the same resources and .class files.

The Spring boot documentation talks about the classpath because it shouldn't make assumptions about how your project is set up.

From Spring documentation

The wildcard classpath relies on the getResources() method of the underlying classloader. As most application servers nowadays supply their own classloader implementation, the behavior might differ especially when dealing with jar files. A simple test to check if classpath* works is to use the classloader to load a file from within a jar on the classpath: getClass().getClassLoader().getResources(""). Try this test with files that have the same name but are placed inside two different locations. In case an inappropriate result is returned, check the application server documentation for settings that might affect the classloader behavior.

So classPath is for load the resources from current class loader (simply for understanding will not read resources under jar or other project dependency)

classpath* will do the jar or other class loader resources.

You can use the loader.path parameter to define a location for an external lib folder. All jars under this folder will be added to the classpath. For example, if you'd like to define C:\extLib as your external lib folder, you can do the following:

java -Dloader.path=/C:/extLib/ -jar aapName.jar

For this to work, you need to use the PropertiesLauncher. There are two ways to do that:

Option 1

Update the project pom.xml and add the following tag:

<configuration>  <!-- added -->
  <layout>ZIP</layout> <!-- to use PropertiesLauncher -->
</configuration>

Effective build tag, the post-update looks like below:

<build> 
    <plugins>
        <plugin>
            <groupId>org.springframework.boot</groupId>
            <artifactId>spring-boot-maven-plugin</artifactId>
            <configuration>  <!-- added -->
                <layout>ZIP</layout> <!-- to use PropertiesLauncher -->
            </configuration>
        </plugin>
    </plugins>
</build>

Option 2

Use the PropertiesLauncher when launching the application from the commandline:

java -cp aapName.jar -Dloader.path=/C:/extLib/ org.springframework.boot.loader.PropertiesLauncher

References:
How to add jars to SpringBoot classpath with jarlauncher

Does classpath: search for resource relative to the document in which it is specified(in case of web applications)?

No, classpath: is always relative to the classpath root. If you put a / at the start of the path, it is silently removed.

Is it more fast to search if i give direct location of resource instead e.g. classpath:/WEB-INF/classes/myfolder/myfile.txt

No, that won't work at all. The classpath root contains /WEB-INF/classes, so the path should be relative to that.

Don't confuse classpath: paths with file paths, they have no relation to each other.